Leybold supports manufacturers in the development of battery technologies
The strategic role of vacuum technology in the development of electric mobility.
Vacuum technology is relevant to the quality and safety of
various stages in the production of lithium-ion batteries. The vacuum specialists at
Leybold have been supporting manufacturers of lithium-ion batteries in their processes
and technological challenges for many years and, as such, have been heavily involved in
the development of electric mobility.
Helping shape developments
Electric mobility is the latest trend in a very dynamic market environment. "From the perspective
of vacuum technology, we have been closely monitoring this evolution for many years," says Dr.
Sina Forster, Business Development Manager at Leybold GmbH. “Having an opportunity to help
shape current developments and research is incredibly exciting,” she adds.
In her opinion, one of the main tasks is to determine new vacuum applications and markets from
new technologies and developments as early as possible. The strategic role of vacuum
technology is therefore to enable and advance these developments. For example, the design of
the vacuum environment is a factor that can have a positive influence on processes. Vacuum is
often used during the electrolyte filling stage to ensure that the cell is evenly saturated with the
electrolyte and to lend purity to the filling process..
Lithium-ion batteries as a vacuum application
Leybold studied developments in this area and identified opportunities for vacuum application in
the manufacturing process of lithium-ion batteries. Because there was initially little information
available regarding the manufacturing process of lithium-ion components, the company joined
forces with Verband Deutscher Maschinen und Anlagenbau (VDMA) and the Chair of
Production Engineering of E-Mobility Components at RWTH Aachen University in order to
establish a manufacturing process. In addition to lithium-ion batteries, Leybold has also been
focusing on developments in fuel cells. Applicable vacuum processes are already emerging,
including the coating of the bipolar plates under vacuum. Here, it’s important to observe the
technological developments over the next few years and, if necessary, to provide support
through cooperation.
Vacuum technology is used in various process steps in electrode manufacture as well as in
research and development. As such, Leybold works closely with machine and plant
manufacturers who supply battery manufacturers with production plants. Additionally, Leybold
cooperates with battery manufacturers as well as with institutions that conduct research to
further develop battery technologies.
Development increasing in Europe
The majority of production continues to take place in Asia. However, much of the research and
development is shifting to Europe, making the EU (and especially Germany) more important as
a research and production location.
Vacuum technology is used in battery cell production as well as in processes such as the
application of active materials to electrodes. "In general, air is a disturbing factor in many
production environments because the millions of particles and gas molecules have a negative
influence on this production step, sometimes even making it impossible. When mixing the slurry,
particles and air bubbles must be avoided in order to achieve a high-quality product. Most
mixers, therefore, work under vacuum," explains Dr. Sina Forster.
Vacuum improves processes
Vacuum is also essential during the drying stage to remove even the smallest remaining
amounts of solvents and moisture. Without vacuum, the drying process would need to be
carried out at much higher temperatures and would last much longer. This would have a
negative effect on the electrode quality. As soon as electrolytes are incorporated into
subsequent process steps, vacuum takes on a safety aspect, since many of the electrolytes
used are highly reactive and inflammable. High-quality vacuum is essential here. On the one
hand, it lends purity to the process so that no particles or moisture can enter the cell during
electrolyte filling and degassing. On the other hand, it provides a low-reaction environment
without oxygen or humidity with which the electrolyte could react.
"The greatest challenge always lies in the gas mixture being pumped. In principle, everything
that's pumped and processed is also transported by the vacuum pump. In battery production,
this affects the solvents and electrolytes which tend to be toxic and can damage the pumps and
possibly the pump oil," says Dr. Sina Forster. "But very warm ambient temperatures and high
humidity are, generally speaking, also circumstances that present us with challenges," she
adds. This is where battery manufacturers are called upon to help, either by ensuring the correct
cooling of the pump or by using condensers.
High-quality drying results under vacuum
Opportunities for improvement exist in many areas, as there are still no established processes
that have proven to be efficient. Vacuum drying, for example, is a customer-specific process of
pressure, temperature and process gases (such as nitrogen). In order to achieve high-quality
drying results through the aid of vacuum drying, industry-related research projects are already
being conducted under the direction of the VDMA.
Leak detection also plays a central role in production from a safety perspective. The cell must
be 100% leak-proof in order to ensure a long battery life. A valid leak test can only be performed
via a vacuum leak detection system. Even the smallest leaks can be detected with the aid of a
helium leak detector or mass spectrometer. On the other hand, undetected leaks greatly shorten
the battery's service life and/or lead to highly-reactive electrolytes escaping.
Some components of lithium-ion batteries that are treated in a vacuum are toxic. In order to
protect the environment and the vacuum technology from pollutants, the vacuum pump must
have the ability to withstand these gases. Additionally, the toxic materials must be confined
within the process and discharged in a correspondingly safe manner.
Dry pumps save time and money
For these toxic gases, dry-running vacuum pumps are used. Oil-sealed vacuum pumps tend to
be unsuitable for these applications, as the pump oil could be damaged or contaminated by the
gases. Using dry-compressing pumps, battery manufacturers save time and money since they
would otherwise need to change the pump oil frequently. “ Oil-sealed vacuum pumps have
increasingly been used in the process of electrolyte filling and degassing, which we are now
replacing with dry-running vacuum pumps for many of our customers," summarizes Dr. Sina
Forster.
In order to ensure sufficient process reliability when handling toxic gases, hermetically-sealed
pumps are used, which prevent even the smallest quantities of gas from escaping. This is an
important factor, especially in the case of toxic electrolytes, where occupational safety is also
important.
Faster and more reliable with vacuum technology
Vacuum technology thus plays an important role in drying, electrolyte filling and degassing.
"Vacuum is essential in all three process steps," underscores Dr. Sina Forster. But upstream
process steps, such as mixing with vacuum mixers, stacking with vacuum grippers and
downstream process steps, such as packaging, are also handled more quickly and reliably with
vacuum technology.
In the future, the influence of a pure vacuum environment and specifications can be even better
determined. With the development of individually-marked electrode sheets which can be traced
through the entire production process using lasered QR codes, the influence of individual
process parameters on battery quality can be accurately traced.
Vacuum ensures the handling of toxic electrolytes
Vacuum technology also plays an important role in terms of safety during battery production and
use. For example, the safe handling of toxic electrolytes in the future will continue to be possible
only under vacuum conditions. Driving electric cars, we trust in the quality of the battery, which
can best be tested and guaranteed under vacuum.
It must be said, however, that processes under vacuum always require more energy than those
under atmospheric pressure. However, enormous progress has been made here in recent years
towards energy-efficient pumps, and today we use highly-economical vacuum pumps in battery
production. "This means that we can now dedicate ourselves to the core questions: How can we
achieve more throughput, safety and quality in battery production by efficiently designing
vacuum systems? And here, too, we'll be making many important advances in the field of
vacuum technology in the coming years," Dr. Sina Forster concludes.
Vacuum technology is relevant to the quality and safety of various stages in the
production of lithium-ion batteries.
Using dry-compressing pumps like Varodry, battery manufacturers save time and
money since they would otherwise need to change the pump oil frequently.